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Trigonal planar

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Theoretical Chemistry

Definition

Trigonal planar refers to a molecular geometry where a central atom is surrounded by three other atoms, positioned at the corners of an equilateral triangle, all in the same plane. This arrangement typically occurs when the central atom has three bonding pairs and no lone pairs of electrons, leading to bond angles of approximately 120 degrees. This geometry is often seen in molecules with sp ext{ } hybridization, where the central atom uses three hybrid orbitals for bonding.

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5 Must Know Facts For Your Next Test

  1. Trigonal planar geometry arises from sp ext{ } hybridization of the central atom, resulting in three equivalent hybrid orbitals.
  2. The bond angles in a trigonal planar configuration are approximately 120 degrees due to the arrangement that minimizes electron pair repulsion.
  3. Common examples of trigonal planar molecules include boron trifluoride (BF ext{ }3) and formaldehyde (CH ext{ }2O).
  4. This molecular geometry can be influenced by the presence of lone pairs; if one or more lone pairs are present, the geometry can change to a different configuration.
  5. Trigonal planar arrangements are important for understanding reactivity and interactions in organic chemistry, particularly in reactions involving double bonds.

Review Questions

  • How does the presence of lone pairs affect the trigonal planar geometry of a molecule?
    • In a trigonal planar geometry, if there are no lone pairs on the central atom, the molecule maintains its shape with bond angles around 120 degrees. However, if one or more lone pairs are present, they will occupy space and create repulsion that can distort the geometry, potentially changing it to a bent or angular shape. This shift in shape influences both molecular properties and reactivity.
  • Compare and contrast trigonal planar geometry with tetrahedral geometry in terms of bond angles and hybridization.
    • Trigonal planar geometry involves sp ext{ } hybridization and features bond angles of approximately 120 degrees due to three bonding pairs arranged in a flat plane. In contrast, tetrahedral geometry results from sp ext{ } hybridization and has four bonding pairs arranged in three-dimensional space, with bond angles of about 109.5 degrees. The differences in electron pair arrangements lead to distinct shapes and angles that affect molecular behavior.
  • Evaluate the implications of trigonal planar geometry on the reactivity and physical properties of organic compounds.
    • Trigonal planar geometry plays a crucial role in determining the reactivity and physical properties of organic compounds. The flat arrangement allows for optimal overlap of p orbitals during reactions involving double bonds, which can lead to higher reactivity compared to other geometries. Additionally, this shape can influence boiling points and solubility due to differences in polarity. Understanding these effects helps chemists predict how molecules will interact in various chemical environments.
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