Physical Chemistry II

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Osmotic pressure

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Physical Chemistry II

Definition

Osmotic pressure is the pressure required to prevent the flow of solvent molecules through a semipermeable membrane when a solute is present. It arises due to the difference in solute concentration on either side of the membrane, driving the solvent to move from an area of lower solute concentration to one of higher solute concentration. This property is significant in understanding colligative properties, as it reflects how solute particles affect the behavior of solvent molecules.

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5 Must Know Facts For Your Next Test

  1. Osmotic pressure can be calculated using the formula $$ ext{π} = iCRT$$, where $$ ext{π}$$ is the osmotic pressure, $$i$$ is the van 't Hoff factor, $$C$$ is the molar concentration of the solute, $$R$$ is the ideal gas constant, and $$T$$ is the absolute temperature.
  2. The osmotic pressure of a solution increases with increasing solute concentration; more solute particles result in a greater tendency for solvent molecules to migrate across the membrane.
  3. Osmotic pressure plays a critical role in biological systems, such as maintaining cell turgor pressure and regulating fluid balance in organisms.
  4. When two solutions of different osmotic pressures are separated by a semipermeable membrane, osmosis will occur until equilibrium is reached, illustrating how solutions strive for equal concentrations.
  5. In practical applications, osmotic pressure principles are utilized in processes such as water purification through reverse osmosis and medical treatments like intravenous solutions.

Review Questions

  • How does osmotic pressure relate to the movement of solvent across a semipermeable membrane?
    • Osmotic pressure is directly related to the movement of solvent molecules across a semipermeable membrane because it quantifies the force needed to prevent that movement. When there is a concentration difference between two solutions separated by a membrane, solvent will naturally flow toward the area with higher solute concentration. This flow continues until osmotic equilibrium is reached, which is determined by balancing osmotic pressure on both sides.
  • Discuss how changing the concentration of a solute affects osmotic pressure and give an example.
    • As the concentration of a solute increases, osmotic pressure also increases. This happens because more solute particles attract more solvent molecules, thereby requiring additional pressure to maintain equilibrium. For example, if you dissolve more salt in water, not only does it take more energy to prevent water from moving into that salt solution but also it demonstrates how solutions strive to equalize concentrations through osmosis.
  • Evaluate how understanding osmotic pressure is essential for applications such as medical treatments and industrial processes.
    • Understanding osmotic pressure is crucial for applications like medical treatments where maintaining proper fluid balance in cells can be life-saving. For instance, intravenous solutions must match the osmotic pressure of blood to avoid causing cells to swell or shrink. In industrial processes such as reverse osmosis used in water purification, controlling osmotic pressure allows for efficient separation of impurities from water, showcasing its importance beyond biological systems.
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