Environmental Chemistry I

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Atom economy

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Environmental Chemistry I

Definition

Atom economy is a measure of the efficiency of a chemical reaction in terms of how well the reactants are converted into useful products. It specifically quantifies the proportion of the total mass of reactants that ends up in the desired product, with higher atom economy indicating less waste and better resource utilization. This concept is crucial for promoting sustainable practices in chemistry by minimizing waste and improving overall efficiency.

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5 Must Know Facts For Your Next Test

  1. Atom economy is calculated using the formula: $$ ext{Atom Economy} = \frac{\text{Molar Mass of Desired Product}}{\text{Total Molar Mass of All Reactants}} \times 100$$.
  2. High atom economy is particularly important in green chemistry as it reduces the formation of by-products, which can be hazardous or costly to dispose of.
  3. Processes with low atom economy often result in significant amounts of waste, making them less sustainable and economically viable.
  4. Improving atom economy can lead to cost savings in raw materials and waste disposal, ultimately benefiting both the environment and businesses.
  5. Atom economy is not only relevant for large-scale industrial reactions but also for laboratory-scale experiments where efficiency can save time and resources.

Review Questions

  • How does atom economy contribute to the principles of green chemistry?
    • Atom economy directly supports green chemistry principles by promoting reactions that maximize the conversion of reactants into desired products while minimizing waste. By focusing on high atom economy, chemists can design processes that are not only more efficient but also generate fewer hazardous by-products. This alignment with sustainability principles helps in reducing environmental impact and promotes safer chemical practices.
  • Evaluate the implications of low atom economy in industrial chemical processes regarding environmental pollution and resource management.
    • Low atom economy in industrial chemical processes typically leads to higher levels of waste production, which can significantly contribute to environmental pollution. When a large portion of reactants does not convert into useful products, it not only wastes resources but also increases the cost of waste management and disposal. This inefficient use of materials can strain local ecosystems and contribute to larger environmental issues, emphasizing the need for improved processes with higher atom economies.
  • Design a hypothetical chemical reaction that maximizes atom economy while considering sustainability factors; explain your rationale.
    • A hypothetical reaction could involve the synthesis of a biodegradable polymer from renewable resources, such as using lactic acid derived from corn starch. By designing a reaction that converts lactic acid directly into polylactic acid (PLA) with minimal by-products, the atom economy would be high since most reactant mass ends up in the desired polymer product. This approach aligns with sustainability by utilizing renewable resources and producing less waste, addressing both environmental concerns and economic viability. Such an efficient process reflects the core principles of green chemistry by promoting sustainable practices.
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